Fluoride Complexation of Element 104, Rutherfordium

6533b853fe1ef96bd12ac1fc

RESEARCH PRODUCT

Fluoride Complexation of Element 104, Rutherfordium

Kazuaki Tsukada S. Ono Naoya Tsuruga Jens Volker Kratz Atsushi Shinohara Kazuhiko Akiyama Toshiyuki Hirai Mitsuru Shigekawa Kaneko Tetsuya Akihiko Yokoyama Atsushi Toyoshima Atsushi Toyoshima Ichiro Nishinaka Yasuji Oura Shinichi Ichikawa Shuich Enomoto Yuichiro Nagame Tsuyoshi Yaita Masato Asai Ken Ichiro Yasuda Hiromitsu Haba Keisuke Sueki Norikazu Kinoshita Minoru Sakama Shin Ichi Goto Matthias Schädel Masaru Hirata Yutaka Miyamoto W. Brüchle Hisaaki Kudo H. Kikunaga Hiromichi Nakahara

subject

Dubnium Ion chromatography Inorganic chemistry Analytical chemistry chemistry.chemical_element General Chemistry Biochemistry Catalysis Partition coefficient chemistry.chemical_compound Colloid and Surface Chemistry Adsorption Hydrofluoric acid chemistry Rutherfordium Fluoride

description

Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

year	journal	country	edition	language
2004-04-02	Journal of the American Chemical Society

https://doi.org/10.1021/ja031824u

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