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RESEARCH PRODUCT

Novel Multifunctional Polymeric Photoinitiators and Photo-Coinitiators Derived from Hyperbranched Polyglycerol

Luc VanmaeleJohan LoccufierEmilie BarriauYu ChenYu ChenHolger Frey

subject

Hyperbranched polyglycerolMaterials sciencePolymers and PlasticsTertiary amineOrganic ChemistryChemical modificationCondensed Matter PhysicsFood packagingEnd-groupPolymer chemistryMaterials ChemistryPhysical and Theoretical ChemistrySolubilityPhotoinitiatorCuring (chemistry)

description

A new class of hyperbranched PPIs and PPCs have been prepared. The introduction of compatibilizing groups such as MEEA or trimethylacetate enhanced their solubility in radiation-curable formulations and led to an improved photoactivity compared with the corresponding MPI and MPC. Although the molecular weights of the subject PPIs and PPCs exceeded 800 g mol -1 , the viscosities of the radiation-curable formulations were still suitable for inkjet application. The combination of high photoactivity, low viscosity, and low extract-ability after curing rendered the resulting hyperbranched PPIs and PPCs attractive as components in the inkjet ink for inkjet printing, e.g., in food packaging.

https://doi.org/10.1002/macp.200700086