6533b853fe1ef96bd12aca6b
RESEARCH PRODUCT
Über Chalkogenocarbonate, XLVI. Darstellung und spektroskopische Eigenschaften einiger Dimethyl‐trichalkogenocarbonate
G. GattowMartin Drägersubject
Inorganic Chemistrychemistry.chemical_classificationchemistry.chemical_compoundAqueous solutionChemistryPhase (matter)Polymer chemistrySalt (chemistry)Methyl iodidedescription
Methyljodid reagiert mit der wasrigen Losung eines leicht loslichen CSe32−-Salzes zu Dimethyltriselenocarbonat und mit der wasrigen Losung eines leicht loslichen CS2Se2−-Salzes zu einem Gemisch aus Dimethyltrithiocarbonat, S.Se-Dimethyl-dithiomonoselenocarbonat und Se.Se′-Dimethyl-monothiodiselenocarbonat. Alle vier Ester bilden in flussiger Phase ein Gemisch aus cis-cis- und cis-trans-Konformeren. On Chalcogenocarbonates, XLVI. Synthesis and Spectroscopic Data of Some Dimethyl Trichalcogenocarbonates By reaction of methyl iodide with an aqueous solution of a readily soluble salt CSe32− dimethyl triselenocarbonate is obtained and by reaction with an aqueous solution of a readily soluble salt CS2Se2− a mixture of dimethyl trithiocarbonate, S.Se-dimethyl dithiomonoselenocarbonate, and Se.Se′-dimethyl monothiodiselenocarbonate. The fluid phases of all these esters are mixtures of cis-cis- and cis-trans-conformers.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1971-05-01 | Chemische Berichte |