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RESEARCH PRODUCT
The non-equilibrium charge screening effects in diffusion-driven systems with pattern formation.
V. N. KuzovkovEugene A. KotominM. Olvera De La Cruzsubject
Surface diffusionChemistryGeneral Physics and AstronomyPattern formationCharge screeningsymbols.namesakeLennard-Jones potentialChemical physicsQuantum mechanicsDebye–Hückel equationCoulombsymbolsMoleculeSPHERESPhysical and Theoretical Chemistrydescription
The effects of non-equilibrium charge screening in mixtures of oppositely charged interacting molecules on surfaces are analyzed in a closed system. The dynamics of charge screening and the strong deviation from the standard Debye-Huckel theory are demonstrated via a new formalism based on computing radial distribution functions suited for analyzing both short-range and long-range spacial ordering effects. At long distances the inhomogeneous molecular distribution is limited by diffusion, whereas at short distances (of the order of several coordination spheres) by a balance of short-range (Lennard-Jones) and long-range (Coulomb) interactions. The non-equilibrium charge screening effects in transient pattern formation are further quantified. It is demonstrated that the use of screened potentials, in the spirit of the Debye-Huckel theory, leads to qualitatively incorrect results.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-07-21 | The Journal of chemical physics |