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RESEARCH PRODUCT

The Kinetics of Excitonic Luminescence in Mixed Silver Halides

Donats MillersEugene A. KotominLarisa GrigorjevaRoberts I. Eglitis

subject

Materials sciencelawKineticsHalideMoleculeIrradiationActivation energyPhotochemistryLuminescenceLaserMolecular physicsSolid solutionlaw.invention

description

ABSTRACTTwo kinds of luminescence (excitonic luminescence and excitonic molecule luminescence) were investigated for solid solutions AgBr1-xClx after pulsed electron beam and N2 laser irradiation. Careful theoretical treatment of a set of experimental excitonic luminescence kinetics is presented. It is shown that the effective activation energy of Agoi migration is a linear function of the composition x. The narrow peak of the excitonic molecule luminescence shifts from 2.66ev in pure AgBr towards higher energies as x increases.

https://doi.org/10.1557/proc-348-309