6533b854fe1ef96bd12ae21b
RESEARCH PRODUCT
Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors
Kari RissanenGerhard RaabeMarkus AlbrechtMarius PetersTim KrappitzMichael GieseArto ValkonenVerena Gossensubject
AnionsBromidesModels MolecularMagnetic Resonance SpectroscopyChemistryHydrogen bondInorganic chemistryChemieMolecular ConformationMetals and AlloysSolid-stateHydrogen BondingCooperativityGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographychemistry.chemical_compoundBromideBenzamidesMaterials ChemistryCeramics and Compositesta116description
A rare anion-π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-09-06 | Chemical Communications |