6533b854fe1ef96bd12ae30c

RESEARCH PRODUCT

Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines

Jas S. WardRosa M. GomilaAntonio FronteraKari Rissanen

subject

jodikemiakemialliset yhdisteethopeasupramolekulaarinen kemiaröntgenkristallografia

description

The silver(I) and iodine(I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(I) complex formation. The complexes were characterised by 1H and 1H–15N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(I) and iodine(I) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions. peerReviewed

yearjournalcountryeditionlanguage
2022-01-01
http://urn.fi/URN:NBN:fi:jyu-202203242050