6533b854fe1ef96bd12aea19

RESEARCH PRODUCT

Effective Henry's law partitioning and the salting constant of glyoxal in aerosols containing sulfate.

Urs BaltenspergerChristopher J. KampfAndré S. H. PrévôtEleanor M. WaxmanRainer VolkamerThorsten HoffmannArnaud P. PraplanJay G. SlowikL. PfaffenbergerJosef Dommen

subject

AerosolsAmmonium sulfateMolalityChromatography010504 meteorology & atmospheric sciencesSulfatesAnalytical chemistryGeneral ChemistryGlyoxal010501 environmental sciencesMass spectrometry01 natural sciencesHenry's lawAerosolchemistry.chemical_compoundchemistryIonic strengthTandem Mass SpectrometryEnvironmental ChemistryGlyoxalSaltsSulfateChromatography High Pressure Liquid0105 earth and related environmental sciences

description

The reversible partitioning of glyoxal was studied in simulation chamber experiments for the first time by time-resolved measurements of gas-phase and particle-phase concentrations in sulfate-containing aerosols. Two complementary methods for the measurement of glyoxal particle-phase concentrations are compared: (1) an offline method utilizing filter sampling of chamber aerosols followed by HPLC-MS/MS analysis and (2) positive matrix factorization (PMF) analysis of aerosol mass spectrometer (AMS) data. Ammonium sulfate (AS) and internally mixed ammonium sulfate/fulvic acid (AS/FA) seed aerosols both show an exponential increase of effective Henry's law coefficients (KH,eff) with AS concentration (cAS, in mol kg(-1) aerosol liquid water, m = molality) and sulfate ionic strength, I(SO4(2-)) (m). A modified Setschenow plot confirmed that "salting-in" of glyoxal is responsible for the increased partitioning. The salting constant for glyoxal in AS is K(S)CHOCHO = (-0.24 ± 0.02) m(-1), and found to be independent of the presence of FA. The reversible glyoxal uptake can be described by two distinct reservoirs for monomers and higher molecular weight species filling up at characteristic time constants. These time constants are τ1 ≈ 10(2) s and τ2 ≈ 10(4) s at cAS12 m, and about 1-2 orders of magnitude slower at higher cAS, suggesting that glyoxal uptake is kinetically limited at high salt concentrations.

10.1021/es400083dhttps://pubmed.ncbi.nlm.nih.gov/23534917