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RESEARCH PRODUCT
Synthesis, properties and charge transfer complexes of covalently attached [60]fullerene-tetrathiafulvalenes
Luis SánchezEnrique OrtíRafael ViruelaRaquel AndreuNazario MartínJavier GarínPedro M. ViruelaJesús OrdunaCarlos Seoanesubject
Materials scienceEthyleneFullereneStereochemistryCharge (physics)General ChemistryCondensed Matter PhysicsCrystallographychemistry.chemical_compoundchemistryCovalent bondIntramolecular forceMoietyGeneral Materials Sciencedescription
Abstract The synthesis of several fulleropyrrolidines bearing differently substitued tetrathiafulvalenes is reported. The synthetic approach used allows the introduction of ethylene spacers between the TTF and the C 60 core. Charge transfer complexes obtained from these [60]fullerene-TTF systems by reaction with tetrafluoro-tetracyano-p-quinodimethane (TCNQF 4 ) show a semiconducting behaviour; theoretical calculations predict an intramolecular CT band from the TTF moiety to the C 60 core.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1997-11-01 |