6533b854fe1ef96bd12aead6

RESEARCH PRODUCT

Dendrimers consisting of stilbene or distyrylbenzene building blocks synthesis and stability

Matthias LehmannHerbert MeierBernhard SchartelManfred Hennecke

subject

ChemistryDendrimerOrganic ChemistryDrug DiscoveryPolymer chemistryConvergent synthesisOrganic chemistryBiochemistry

description

Abstract On the basis of Wittig-Horner reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers ( 2a-c, 2a'-c' ) which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units.

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