6533b854fe1ef96bd12aeb5b
RESEARCH PRODUCT
Incorporation of potassium halides in the mechanosynthesis of inorganic perovskites: feasibility and limitations of ion-replacement and trap passivation
Yousra El AjjouriHenk J. BolinkFrancisco PalazonVladimir S. ChirvonyMichele Sessolosubject
Materials sciencePhotoluminescencePassivationGeneral Chemical EngineeringPotassiumInorganic chemistryHalidechemistry.chemical_element02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesIonTrap (computing)chemistryMechanosynthesis0210 nano-technologyLayer (electronics)MaterialsFisicoquímicadescription
Potassium halides (KX; X = I, Br, or Cl) were incorporated as partial replacements of CsBr in the mechanosynthesis of CsPbBr3. This led to partial substitution of both monovalent ions forming mixed Cs1−xKxPbBr3−yXy perovskites. Longer photoluminescence lifetimes were also observed, possibly linked to the formation of a non-perovskite KPb2X5 passivating layer.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-10-24 | RSC Advances |