6533b854fe1ef96bd12af1cf
RESEARCH PRODUCT
“Supramolecular” Solid-State Chemistry: Interpenetrating Diamond-Type Frameworks of U4+ Ions Linked byS,S′-Bidentate P2S62− Molecular Rods in UP4S12
Wolfgang TremelFrank RockerVadim KsenofontovChristine GieckPhilipp Gütlichsubject
Solid-state chemistryMaterials scienceDenticityCoordination polymerInorganic chemistrySupramolecular chemistryGeneral ChemistryCatalysisRodIonDiamond typeCrystallographychemistry.chemical_compoundchemistrydescription
Inseparably interwoven are three independent polymeric diamond-type U(P2 S6 )2 frameworks in the structure of the title compound. The linear P2 S6 units act as molecular rods linking the pseudotetrahedral U4+ centers. U(P2 S6 )2 may be viewed as a coordination polymer which is formed from U/P/S melts by the solid-state equivalent of the self-assembly reactions in solution.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2001-03-02 | Angewandte Chemie International Edition |