0000000000160918
AUTHOR
Frank Rocker
„Supramolekulare“ Festkörperchemie: einander durchdringende diamantartige Gerüststrukturen mit U4+-Ionen und zweizähnigen molekularen P2S62−-S,S′-„Stäben“ in UP4S12
Synthesis and Structure of ThTe2I2
Metal-Organic Chemical Vapor Depostion Synthesis of Hollow Inorganic-Fullerene-Type MoS2 and MoSe2 Nanoparticles
ChemInform Abstract: Synthesis and Structure of ThTe2I2.
Modular Metal Chalcogenide Chemistry: Secondary Building Blocks as a Basis of the Silicate-Type Framework Structure of CsLiU(PS4)2
The novel uranium thiophosphate CsLiU(PS4)2 has been synthesized by reacting uranium metal, Cs2S, Li2S, S, and P2S5 at 700 °C in an evacuated silica tube. The crystal structure was determined by single-crystal X-ray diffraction techniques. CsLiU(PS4)2 crystallizes in the rhombohedral space group Rc (a = 15.2797(7) A; c = 28.778(2) A, V = 5818.7(5) A3, Z = 18). The structure ofCsLiU(PS4)2 is a unique three-dimensional U(PS4)22– framework with large tunnels with an approximate diameter of 6.6 A running parallel to the crystallographic c axis. The tunnels are filled with Cs+ cations. The smaller Li+ cations are located at tetrahedral sites at the periphery of the channels. In the structure of …
Metal—Organic Chemical Vapor Deposition Synthesis of Hollow Inorganic-Fullerene-Type MoS2 and MoSe2 Nanoparticles.
VS2 nanotubes containing organic-amine templates from the NT-VOx precursors and reversible copper intercalation in NT-VS2.
Selective Synthesis of Hollow and Filled Fullerene-like (IF) WS2 Nanoparticles via Metal–Organic Chemical Vapor Deposition
The synthesis of WS2 onion-like nanoparticles by means of a high-temperature metal–organic chemical vapor deposition (MOCVD) process starting from W(CO)6 and elemental sulfur is reported. The react...
ChemInform Abstract: Modular Metal Chalcogenide Chemistry: Secondary Building Blocks as a Basis of the Silicate-Type Framework Structure of CsLiU(PS4)2.
The new title compound is synthesized from a mixture of U, P2S5, Li2S, Cs2S, and S in the molar ratio 2:2:1:1:4 (sealed silica tube, 700 °C, 3 d).
VS2-Nanoröhren mit Amin-Templaten der VOx-Vorstufen und reversible Cu-Einlagerung in NT-VS2
“Supramolecular” Solid-State Chemistry: Interpenetrating Diamond-Type Frameworks of U4+ Ions Linked byS,S′-Bidentate P2S62− Molecular Rods in UP4S12
Inseparably interwoven are three independent polymeric diamond-type U(P2 S6 )2 frameworks in the structure of the title compound. The linear P2 S6 units act as molecular rods linking the pseudotetrahedral U4+ centers. U(P2 S6 )2 may be viewed as a coordination polymer which is formed from U/P/S melts by the solid-state equivalent of the self-assembly reactions in solution.