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RESEARCH PRODUCT
Synthesis highly active platinum tri-metallic electrocatalysts using "one-step" organometallic chemical vapour deposition technique for methanol oxidation process
Leslie F. PetrikQ NaidooQ NaidooSivapregasen NaidooPatrick NdunguGuntars VaivarsAlexander Nechaevsubject
Materials scienceInorganic chemistryAlloychemistry.chemical_elementChemical vapor depositionCarbon nanotubeengineering.materialCatalysislaw.inventionMetalchemistry.chemical_compoundchemistrylawvisual_artvisual_art.visual_art_mediumengineeringMethanolCyclic voltammetryPlatinumdescription
A simple solvent free method for the synthesis of tri-metallic platinum electrocatalysts on carbon nanotubes is presented. By investigating the platinum alloy electrocatalysts, it was showed that the additional metals of platinum alloys could reduce the metal particle sizes and produce larger chemical-active surface area, as well as the higher methanol oxidation activity of the catalysts. The organometallic chemical vapour deposition method was successfully applied to produce multiple samples of PtRuFe, PtRuCu and PtRuV. The electrocatalysts were characterized by ICP, XRD, HRTEM and the catalytic activity was determined by cyclic voltammetry (CV).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-08-20 | IOP Conference Series: Materials Science and Engineering |