6533b855fe1ef96bd12b0893
RESEARCH PRODUCT
Diferrocenyl tosyl hydrazone with an ultrastrong NHFe hydrogen bond as double click switch.
Christoph FörsterKatja HeinzeVadim KsenofontovPhilipp Veitsubject
chemistry.chemical_classificationHydrogen bondMetals and AlloysHydrazoneGeneral ChemistryPhotochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundElectron transferchemistryTosylIntramolecular forceMaterials ChemistryCeramics and Compositesdescription
The intramolecular NH⋯Fe hydrogen bond in diferrocenyl hydrazone 2 raises the barrier for intramolecular electron transfer in its mixed-valent cation 2+ and is only disrupted by double oxidation to 22+.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-12-16 | Chemical communications (Cambridge, England) |