6533b855fe1ef96bd12b09ca
RESEARCH PRODUCT
Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages
Niklas StruchKari RissanenArne LützenFilip Topićsubject
DiffractionTrifluoromethyl010405 organic chemistryLigandSupramolecular chemistry010402 general chemistryMass spectrometry01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryelectron-deficient trifluoromethyl-substituted sub-componentsTetrahedronSpectroscopyta116Single crystaldescription
Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | Dalton Transactions |