6533b855fe1ef96bd12b1188

RESEARCH PRODUCT

On the reaction of [Ph2(OH)Si]2O with t-Bu2SnCl2: Synthesis and characterization of the first well defined polystannasiloxane [(t-Bu2SnO)(Ph2SiO)2]n

Dieter SchollmeyerJens BeckmannKlaus JurkschatMarkus Schürmann

subject

chemistry.chemical_classificationSiliconOrganic Chemistrychemistry.chemical_elementPolymerCharacterization (mathematics)Ring (chemistry)BiochemistryInorganic ChemistryCrystallographychemistryYield (chemistry)X-ray crystallographyMaterials ChemistryPhysical and Theoretical ChemistryWell-definedTin

description

Abstract The high yield synthesis of [(t-Bu2SnO)(Ph2SiO)2], 1 is reported. Compound 1 is a linear polymer in the solid state but a six-membered ring in solution.

https://doi.org/10.1016/s0022-328x(97)00263-5