6533b855fe1ef96bd12b11f6

RESEARCH PRODUCT

Influence of the Ce: YAG amount on structure and optical properties of Ce:YAG-PMMA composites for white LED

Maria Luisa SaladinoFrancesco ArmettaDelia Francesca Chillura MartinoM. A. SibekoAlberto SpinellaAdriaan S. Luyt

subject

Materials sciencegenetic structuresbusiness.industryWhite LEDPolymeric Composites02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyPMMA01 natural sciencesInterface InteractionsYAG [Ce]eye diseases0104 chemical sciencesOptoelectronicsComposite materialPhysical and Theoretical Chemistry0210 nano-technologybusiness

description

Ce:YAG-poly(methyl methacrylate) (PMMA) composites were prepared by using a melt compounding method, adding several amounts of Ce:YAG in the range 0.1–5wt.%. The optical properties of the obtained composites and of the composites combined with a blue LED were measured to investigate the effect of the amount of Ce:YAG on the resulting emitted light in view of possible application in white LED manufacture. An increase in Ce:YAG amount caused an increase in the emission and a shift of 15 nm, influencing the white LED performance. The structure and morphology of the composites were studied. The results show that the interaction between the two components, observed by using solid state NMR experiments, are the responsible for the observed shift. The authors acknowledge the University of Palermo, FFR 2012–2013 –ATE 0594 and CORI2013

10.1515/zpch-2015-0703http://hdl.handle.net/10447/212699