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RESEARCH PRODUCT

Synthesis, characterisation, crystal structures, and magnetic properties of one-dimensional oxalato-bridged metal(II) complexes with 3-hydroxypyridine and isoquinoline

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One-dimensional oxalato-bridged metal(II) compounds of formula [M(-ox)(L)2]n [L = 3-hydroxypyridine (pyOH) or isoquinoline (isq)] have been synthesised and characterised by FT-IR spectroscopy, TG-DTA techniques, variable-temperature magnetic measurements and X-ray diffraction methods. The complexes [M(-ox)(pyOH)2]n [M= Co (1), Ni (2)] are isomorphous and crystallise in the orthorhombic space group Pnab. The compounds [M(-ox)(isq)2]n [M= Co (3), Ni (4), Cu (5)] are also isomorphous and belong to the monoclinic space group C2/c. Crystal structures consist of zig-zag chains in which cis-[M(L)2] 2 + units are sequentially bridged by bis-bidentate oxalato ligands with intrachain M···M distances in the range 5.38–5.49 A . The divalent metal centres have a distorted octahedral coordination with four oxygen atoms from two symmetry-related bridging oxalato ligands and the pyridinic nitrogen atoms from two cis-oriented aromatic ligands. Magnetic susceptibility measurements in the temperature range 2.0–300 K show the occurrence of antiferromagnetic intrachain interactions for the compounds 1– 4 and a weak ferromagnetic coupling for 5. © 2001 Elsevier Science B.V. All rights reserved.