6533b856fe1ef96bd12b26db

RESEARCH PRODUCT

[MIII(bpym)(CN)4]−: a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym = 2,2′-bypyrimidine)

Catalina Ruiz‐pérezOscar FabeloMiguel JulveDiana VisinescuFrancesc LloretLuminita Marilena Toma

subject

Inorganic ChemistryDc fieldCrystallographyMaterials scienceCondensed matter physicsFerrimagnetismBlock (telecommunications)Metamagnetism

description

Two cyano-bridged M(III)Mn(III) [M = Fe () and Cr ()] ferrimagnetic chains are reported; exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the overcoming by the applied dc field of the inter- and intrachain magnetic interactions, respectively.

https://doi.org/10.1039/b809160a