6533b856fe1ef96bd12b2eac

RESEARCH PRODUCT

Crystal structure, magnetic properties and Mössbauer studies of [Fe(qsal)2][Ni(dmit)2]

José Antonio RealBénédicte Garreau De BonnevalGábor MolnárStéphane LampertAzzedine BousseksouStéphane DorbesLydie ValadeChristophe FaulmannKane Jacob

subject

Inorganic ChemistryCrystallographySpin crossoverChemistryMössbauer spectroscopyMaterials ChemistryCrystal structurePhysical and Theoretical Chemistry

description

Abstract A new compound of formula [Fe(qsal)2][Ni(dmit)2] (1) has been synthesised, structurally and magnetically characterised (qsalH = N-(8-quinolyl)salicylaldimine, dmit2− = 1,3-dithiol-2-thione-4,5-dithiolato). Its structural features and its magnetic behaviour were compared with those of [Fe(qsal)2]-based complexes, and more particularly [Fe(qsal)2][Ni(dmit)2] · 2CH3CN.

yearjournalcountryeditionlanguage
2007-10-01Inorganica Chimica Acta
https://doi.org/10.1016/j.ica.2007.03.022