6533b856fe1ef96bd12b2ed7

RESEARCH PRODUCT

Direct determination of calcium, magnesium, sodium and potassium in water by flow injection flame atomic spectroscopy, using a dilution chamber

Amparo SalvadorV. CarbonellA. MoralesM. De La Guardia

subject

Flow injection analysisMagnesiumSodiumPotassiumClinical BiochemistryAnalytical chemistrychemistry.chemical_elementGeneral MedicineAtomic spectroscopyAnalytical Chemistrylaw.inventionDilutionchemistrylawLanthanumGeneral Materials ScienceAtomic absorption spectroscopy

description

A simple procedure to carry out the direct analysis of calcium, magnesium, sodium and potassium in water by flow injection analysis (FIA) using flame atomic absorption spectroscopy (AAS) or flame photometry (FP) has been developed, using a well stirred dilution chamber to extend the calibration range, and both a double injector and the merging zone technique to add a lanthanum solution to samples and standards. The results obtained in the analysis of real samples agree with those found by a batch flame atomic procedure. The use of the dilution chamber makes it possible to carry out the calibration using the dilution profile of a single concentrate standard for each element, and an empirical dilution equation, which could be employed for all the elements is determined in each work session.

https://doi.org/10.1007/bf00466392