6533b856fe1ef96bd12b30d5
RESEARCH PRODUCT
One pot microwave assisted synthesis of bisphosphonate alkene capped gold nanoparticles
Romain AufaureYoann LalatonneOlivier HeintzErwann GuéninN. LièvreLaurence Mottesubject
Materials scienceGeneral Chemical EngineeringInorganic chemistry02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesMicrowave assisted[ CHIM ] Chemical SciencesMetalColloidCoating[CHIM]Chemical SciencesMoleculechemistry.chemical_classificationAlkeneGeneral Chemistry021001 nanoscience & nanotechnologyCombinatorial chemistry0104 chemical scienceschemistryColloidal goldvisual_artengineeringvisual_art.visual_art_mediumParticle size0210 nano-technologydescription
International audience; A new synthetic pathway for the direct synthesis of water soluble gold nanoparticles (GNPs) already possessing terminal alkene functional groups was developed. This is achieved by using synthesized (1-hydroxy-1-phosphonopent-4-enyl)phosphonic acid (HMBPene), presenting advantages of the well known bisphosphonate coating applied to colloidal gold instead of metal oxides. The proposed protocol allowed an accurate control of the particle size in the 13–20 nm diameter range with a high spherical uniformity, which is a crucial point for these colloids' properties. We have shown that it is possible to synthesize a functionalized nanoplatform in a one-pot one-phase process with a sacrificial molecule as reductant, pH mediator and capping agent.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-01-01 |