Darstellung und Eigenschaften einiger Phosphorverbindungen mit tert.‐Butylgruppen

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Darstellung und Eigenschaften einiger Phosphorverbindungen mit tert.‐Butylgruppen

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Einfache Verfahren zur Darstellung von Di-tert.-butylphosphin, tert.-Butyl-phenyl-phosphin und tert.-Butyl-phenyl-phosphinoxyd werden beschrieben. Das Reaktionsverhalten dieser Verbindungen sowie der aus den sekundaren Phosphinen durch Alkylierung erhaltenen tertiaren Phosphine mit einer oder zwei tert.-Butylgruppen wird untersucht. Bei der Umsetzung von Methyl-tert.-butyl-phenyl-phosphin oder Triphenylphosphin mit Tritylchlorid erhalt man p-Benzhydrylphenyl-phosphoniumsalze.

year	journal	country	edition	language
1966-04-01	Chemische Berichte

https://doi.org/10.1002/cber.19660990408

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