6533b857fe1ef96bd12b4d1d
RESEARCH PRODUCT
The Swelling Behavior of Polyelectrolyte Multilayers in Air of Different Relative Humidity and in Water
Ralf KüglerWolfgang KnollJohannes Schmittsubject
chemistry.chemical_classificationAqueous solutionPolymers and PlasticsOrganic ChemistrySurface plasmonSorptionPolymerCondensed Matter PhysicsPolyelectrolytechemistryPolymer chemistryMaterials ChemistrymedicineRelative humidityNeutron reflectometryPhysical and Theoretical ChemistrySwellingmedicine.symptomdescription
The swelling properties of physisorbed polyelectrolyte multilayer self-assemblies with alternating polyion charge in humid air and in aqueous environment were investigated via X-ray and neutron reflectometry as well as optically, using surface plasmon spectroscopy. The sorption behavior was similar to that found for neutral polymers and was related to an internal screening of the charges of the adjacent layers owing to the high entanglement of the polyelectrolyte chains and the resulting low mobility of the polymer segments. The screening was found to be incomplete only in the top layer, resulting in a net charged surface.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-01-01 | Macromolecular Chemistry and Physics |