6533b857fe1ef96bd12b4d71
RESEARCH PRODUCT
The generalized H-point standard-additions method to determine analytes present in two different chemical forms in unknown matrix samples. Part I. General considerations
Pilar Campíns-falcóLuis Antonio Tortajada-genaroFrancisco Bosch-reigF. Blasco-gómezsubject
Systematic errorAnalyteInternal standardChemistrySample (material)Analytical chemistryBiochemistryAnalytical ChemistryMatrix (chemical analysis)ChemometricsStandard additionElectrochemistryEnvironmental ChemistryPoint (geometry)Spectroscopydescription
This paper shows how the generalized H-point standard-additions method (GHPSAM) can be used to obtain the total concentration or concentrations of different chemical forms of an analyte when the matrix of the sample is completely unknown. The spectral regions where the interferent behaviour can be considered as linear are found and the analyte concentration free from bias error is estimated. This paper includes the already published features of the GHPSAM and a new modification of this method which allows the simultaneous determination of two chemical forms of an analyte in a sample.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-01-01 | The Analyst |