6533b858fe1ef96bd12b5c7b

RESEARCH PRODUCT

Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds

Shilin YuElina KaleniusAntonio FronteraKari Rissanen

subject

jodikemialliset sidoksethalogeenitkompleksiyhdisteet

description

New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-202112025867