6533b858fe1ef96bd12b65ad

RESEARCH PRODUCT

Secondary relaxation in the glass-transition regime of ortho-terphenyl observed by incoherent neutron scattering.

Winfried PetryF. FujaraM. KiebelEckhard BartschO. DebusHans Sillescu

subject

Materials scienceCondensed matter physicsIncoherent scatterNeutron scatteringCondensed Matter::Disordered Systems and Neural NetworksCondensed Matter::Soft Condensed Mattersymbols.namesakechemistry.chemical_compoundchemistryCritical point (thermodynamics)TerphenylPicosecondsymbolsPhysics::Chemical Physicsvan der Waals forceGlass transitionSupercooling

description

We report on incoherent-neutron-scattering measurements in the supercooled regime of the van der Waals liquid ortho-terphenyl. A secondary localized relaxational process on the picosecond time scale is found. In accordance with mode-coupling theories of the glass transition, the relaxational dynamics around a critical temperature ${\mathit{T}}_{\mathit{c}}$ decomposes into two time regimes.

10.1103/physrevb.45.10301https://pubmed.ncbi.nlm.nih.gov/10000933