6533b859fe1ef96bd12b77e2
RESEARCH PRODUCT
Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure
Jorge PasánEmilio PardoJesús Ferrando-soriaThais GranchaFrancesc LloretMarta MonYves Journauxsubject
Coordination polymerCationic polymerizationStructure (category theory)chemistry.chemical_elementCopper3. Good healthIonInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryMagnet[CHIM]Chemical SciencesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSdescription
A unique chiral three-dimensional magnet with an overall racemic double-interpenetrated (10,3)-a structure of the formula [(S)-(1-PhEt)Me3N]4[Mn4Cu6(Et2pma)12](DMSO)3]·3DMSO·5H2O (1; Et2pma = N-2,6-diethylphenyloxamate) has been synthesized by the self-assembly of a mononuclear copper(II) complex acting as a metalloligand toward Mn(II) ions in the presence of a chiral cationic auxiliary, constituting the first oxamato-based chiral coordination polymer exhibiting long-range magnetic ordering.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-09-01 | Inorganic Chemistry |