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RESEARCH PRODUCT
Isobaric Vapor−Liquid Equilibria of the Water + 1-Propanol System at 30, 60, and 100 kPa
And Juan B. MontónCarmen GabaldónPaula MarzalManuel A. Rodrigosubject
Activity coefficientBoiling pointUNIQUACVapor pressureChemistryGeneral Chemical EngineeringBoilingAzeotropeNon-random two-liquid modelThermodynamicsIsobaric processGeneral Chemistrydescription
Isobaric vapor−liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness−Byer−Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1996-01-01 | Journal of Chemical & Engineering Data |