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RESEARCH PRODUCT
Glassy dynamics in monodisperse hard ellipsoids
Patrick PfleidererTanja SchillingKristina Milinkovićsubject
Materials scienceIsotropyDynamics (mechanics)Dispersity: Physics [G04] [Physical chemical mathematical & earth Sciences]General Physics and AstronomyFOS: Physical sciencesDisordered Systems and Neural Networks (cond-mat.dis-nn)Condensed Matter - Soft Condensed MatterCondensed Matter - Disordered Systems and Neural NetworksEllipsoidlaw.inventionCondensed Matter::Soft Condensed Matter: Physique [G04] [Physique chimie mathématiques & sciences de la terre]lawChemical physicsPhase (matter)Relaxation (physics)ParticleSoft Condensed Matter (cond-mat.soft)CrystallizationDiffusion (business)description
We present evidence from computer simulations for glassy dynamics in suspensions of monodisperse hard ellipsoids. In equilibrium, almost spherical ellipsoids show a first order transition from an isotropic phase to a rotator phase. When overcompressing the isotropic phase into the rotator regime, we observe super-Arrhenius slowing down of diffusion and relaxation, accompanied by two-step relaxation in positional and orientational correlators. The effects are strong enough for asymptotic laws of mode-coupling theory to apply. Glassy dynamics are unusual in monodisperse systems. Typically, polydispersity in size or a mixture of particle species is prerequisite to prevent crystallization. Here, we show that a slight particle anisometry acts as a sufficient source of disorder. This sheds new light on the question of which ingredients are required for glass formation.
year | journal | country | edition | language |
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2008-02-21 |