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RESEARCH PRODUCT
Development of the Dipole Moment and Polarizability Operators of Octahedral Molecules
Vincent BoudonN CheblalMichel Loetesubject
PhysicsBond dipole momentTransition dipole momentTetrahedral molecular geometryRotational–vibrational spectroscopyMolecular physicsAtomic and Molecular Physics and Opticssymbols.namesakeDipoleStark effectPolarizabilityQuantum mechanicsPhysics::Atomic and Molecular ClusterssymbolsMoleculePhysics::Atomic PhysicsPhysics::Chemical PhysicsPhysical and Theoretical ChemistrySpectroscopydescription
We present a development of the dipole moment and polarizability operators of octahedral molecules, using a tensorial formalism analogous to the one developed for tetrahedral molecules. These operators are involved in the calculation of the intensities of rovibrational transitions as well as in the calculation of the Stark effect. Expressions for the matrix elements are derived. Two simplified models for the study of the Stark effect in such molecules are also proposed and discussed. Copyright 1999 Academic Press.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-11-30 | Journal of Molecular Spectroscopy |