Über Lichtreaktionen, XIV Bildung und Chemische Eigenschaften photolytisch erzeugter Arylimene

6533b85afe1ef96bd12b8a5a

RESEARCH PRODUCT

Über Lichtreaktionen, XIV Bildung und Chemische Eigenschaften photolytisch erzeugter Arylimene

Leopold Horner Albrecht Christmann Albert Gross

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Bei der Photolyse und Thermolyse von Arylaziden entstehen, wahrscheinlich uber Arylimene, Azoaryle. Elektronenspendende Substituenten im Arylazid sowie geeignete Losungsmittel erhohen die Ausbeute an Azoarylen. Im Kreuzversuch mit verschiedenen Arylaziden entstehen unsymmetrische Azoaryle. Bei gleichzeitiger Belichtung von 4-Azido-biphenyl und 9-Diazo-fluoren wird 4-Fluorenyliden-amino-biphenyl(VI) gebildet. Bei der Photolyse von Phenylazid in Eisessig entstehen in masiger Ausbeute p-Amino-phenol-diacetat und o-Acetaminophenol. α-Azido-styrol wird auch photolytisch in 2-Phenyl-azirin umgewandelt.

year	journal	country	edition	language
1963-02-01	Chemische Berichte

https://doi.org/10.1002/cber.19630960206

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