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RESEARCH PRODUCT
Synthesis and characterization of bi-functional photorefractive polymers
Yuankang HeFeng WangQihuang GongYiwang ChenHuiying Chensubject
Acrylate polymerchemistry.chemical_classificationAcrylateAzo compoundPolymers and PlasticsPhotoisomerizationChemistryOrganic ChemistryPhotorefractive effectPolymerPhotochemistrychemistry.chemical_compoundPolymer chemistryMaterials ChemistrySide chainMoietydescription
Abstract A novel bi-functional photorefractive acrylate polymer with pendant carbazolyl groups and azo derivatives as side chains was synthesized, in which azo derivatives as electro-optic chromophores and carbazolyl as photoconductive moiety were covalently linked on the acrylate backbone. Photorefractive experiments showed that a high two-beam coupling gain coefficient of 93 cm −1 , diffraction efficiency of 12% and electro-optic coefficient of 26 pm/V were obtained. With increasing writing beam's intensity, the two-beam coupling enhanced gradually, and then reached saturation. Using the method of four-wave mixing, the photoisomerization grating was observed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2001-02-01 | Polymer |