6533b85afe1ef96bd12b94dd
RESEARCH PRODUCT
Highly diastereoselective additions of organometallic reagents to 1-O-silylated 3,4-Di-O-benzyl-L-erythrulose derivatives
Miguel CardaJ. Alberto MarcoFlorenci V. GonzálezSantiago Rodríguezsubject
Inorganic Chemistrychemistry.chemical_compoundNucleophilic additionchemistryReagentOrganic ChemistryOrganic chemistryChelationPhysical and Theoretical ChemistryL-ERYTHRULOSECarbonyl groupCatalysisdescription
Abstract The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of the title compounds has been investigated. Some organomagnesium reagents display high diastereoselectivities (90–99%) and the major products are those predicted by the α-chelation model.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-08-01 | Tetrahedron: Asymmetry |