6533b85afe1ef96bd12b95a8

RESEARCH PRODUCT

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

Fu-sheng GuoRichard A. LayfieldBenjamin M. DayBenjamin M. DayYan-cong ChenAkseli MansikkamäkiMing-liang Tong

subject

agnetic propertiesmagneettiset ominaisuudetchemistry.chemical_elementorganometalliyhdisteet010402 general chemistry01 natural sciencesMagnetizationchemistry.chemical_compoundMoleculeSingle-molecule magnetsingle-molecule magnetsrare earth metalsta116MultidisciplinaryCondensed matter physics010405 organic chemistryrganometallic compoundskompleksiyhdisteetmetallocenesharvinaiset maametallitMagnetic hysteresismagnetic hysteresisNanomagnet0104 chemical scienceschemistryMagnetDysprosiumQD0146Metallocene

description

Breaking through the nitrogen ceiling Single-molecule magnets could prove useful in miniaturizing a wide variety of devices. However, their application has been severely hindered by the need to cool them to extremely low temperature using liquid helium. Guo et al. now report a dysprosium compound that manifests magnetic hysteresis at temperatures up to 80 kelvin. The principles applied to tuning the ligands in this complex could point the way toward future architectures with even higher temperature performance. Science , this issue p. 1400

https://doi.org/10.1126/science.aav0652