6533b85afe1ef96bd12b980f

RESEARCH PRODUCT

Gas chromatography of homologous esters

J.k. HakenIlpo O.o. Korhonen

subject

Steric effectsCapillary actionCarboxylic acidchemistry.chemical_elementBranching (polymer chemistry)BiochemistryAnalytical ChemistryHomologous serieschemistry.chemical_compoundCapillary columnpolycyclic compoundsChlorineOrganic chemistryChlorine substituentAlkylchemistry.chemical_classificationDegree of unsaturationChromatographyOrganic ChemistryChloroacetatesGeneral MedicinechemistryAcyl chainKovats retention indexNon polarGas chromatographyAliphatic compound

description

Abstract The gas chromatographic retention behaviour of the propanoyl and monochloropropanoyl esters of saturated C3C5 branched-chain and unsaturated C3C6 alcohols on SE-30 and OV-351 capillary columns at several temperatures is reported. Retention index increments at 80 and 120°C show the effect of branching in the alkyl chain and also the effect of unsaturation and of its position in the chain with chlorination at the two possible positions in the acyl chain. The various incremental effects are discussed and compared with the behaviour of the corresponding n-alkyl esters.

yearjournalcountryeditionlanguage
1984-01-01Journal of Chromatography A
https://doi.org/10.1016/s0021-9673(00)91468-7