Synthesis and Reactivity of Ortho-Mercuriated and Ortho-Palladated Arylacetals and Cyclic and Acyclic Aryldithioacetals. New Examples of the Rearrangement of Acyclic Dithioacetal Aryl- to Dithioether Alkyl-Palladium Complexes

6533b85afe1ef96bd12b9e9e

RESEARCH PRODUCT

Synthesis and Reactivity of Ortho-Mercuriated and Ortho-Palladated Arylacetals and Cyclic and Acyclic Aryldithioacetals. New Examples of the Rearrangement of Acyclic Dithioacetal Aryl- to Dithioether Alkyl-Palladium Complexes

M. Carmen Ramírez De Arellano Francisco S. Hernandez-mata José-antonio Abad José Vicente Peter G. Jones Barbara Rink

subject

Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound chemistry Stereochemistry Aryl Organic Chemistry chemistry.chemical_element Reactivity (chemistry)Physical and Theoretical Chemistry Medicinal chemistry Alkyl Palladium

description

The arylmercurial [Hg{C6H3(CHO)2-2,5}Cl] (1) reacts with CH(OMe)3 or HS(CH2)2SH to give [Hg{C6H3{CH(OMe)2}2-2,5}Cl] (2) or [Hg(Ara)Cl] [Ara = C6H3{CH(SCH2CH2S)}2-2,5 (3a)], respectively. The mercur...

year	journal	country	edition	language
2004-02-18	Organometallics

https://doi.org/10.1021/om0342964

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