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RESEARCH PRODUCT
ChemInform Abstract: Palladium on Pumice: New Catalysts for the Stereoselective Semihydrogenation of Alkynes to (Z)-Alkenes.
Renato NotoLeonarda F. LiottaMichelangelo GruttadauriaGiulio Deganellosubject
Ethanolchemistry.chemical_elementEthylenediamineGeneral MedicineTriple bondCatalysischemistry.chemical_compoundchemistryPumicePolymer chemistryOrganic chemistryStereoselectivityTetrahydrofuranPalladiumdescription
Abstract High selectivities (93–99%) and excellent stereoselectivities (>99%) in the semihydrogenation of CC triple bonds were achieved using palladium on pumice with a metal loading of 0.5, 1.5 or 3.0% wt as catalyst. The reactions were carried out in ethanol or tetrahydrofuran with only 2.5% of ethylenediamine allowing a self-terminating semihydrogenation independently on the CC triple bond.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-05-25 | ChemInform |