6533b85afe1ef96bd12ba0ac
RESEARCH PRODUCT
Towards the synthesis of substituted porphyrins by a pyridyl group bearing a reactive functionality
Benoit HabermeyerClaude P. GrosJean-michel BarbeMaya El Ojaimisubject
010405 organic chemistryChemistryStereochemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryGeneral Chemistry010402 general chemistry01 natural sciencesPorphyrinCoupling reaction0104 chemical sciencesA3B-porphyrinschemistry.chemical_compoundSuzuki reactionGroup (periodic table)[ CHIM.ORGA ] Chemical Sciences/Organic chemistryPolymer chemistrypolycyclic compoundsMoietyMoleculeheterocyclic compoundsReactivity (chemistry)meso-functionalizationSuzuki couplingpyridyl substituted porphyrinsComputingMilieux_MISCELLANEOUSdescription
Pyridyl-substituted porphyrins bearing a reactive functionality were prepared via Suzuki cross-coupling reactions and resulted in very good yields. These compounds are precursors of new porphyrin architectures able to coordinate two metals: one in the porphyrin core and the second around the pyridyl moiety. During the coupling reactions, a higher reactivity of a chloro picolyl group was evidenced compared to a bromo function on the same reacting molecule.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-06-01 |