Synthesis of Fluorinated Bent-Core Mesogens (BCMs) Containing the 1,2,4-Oxadiazole Ring

6533b85bfe1ef96bd12ba979

RESEARCH PRODUCT

Synthesis of Fluorinated Bent-Core Mesogens (BCMs) Containing the 1,2,4-Oxadiazole Ring

Antonio Palumbo Piccionello Silvestre Buscemi Ivana Pibiri Alessandro Calabrese Andrea Pace Valentina Giacalone

subject

Small-angle X-ray scattering Chemistry Organic Chemistry Bent molecular geometry Mesophase Oxadiazole 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Ring (chemistry)01 natural sciences 0104 chemical sciences Core (optical fiber)chemistry.chemical_compound Nucleophile Polymer chemistry Reactivity (chemistry)0210 nano-technology

description

New fluorinated bent-core mesogens containing the 1,2,4-oxadiazole or 1,2,4-triazole nucleus have been synthesized taking advantage of the ANRORC (Addition of Nucleophile, Ring-Opening, Ring-Closure) reactivity of 5-perfluoroalkyl-1,2,4-oxadiazoles. Physical state changes of the obtained compounds were characterized through DSC, POM, and SAXS. Besides the formation of a smectic mesophase, a novel behavior as organic molecular glass was evidenced for some 1,2,4-oxadiazole derivatives.

year	journal	country	edition	language
2015-09-11	Journal of Heterocyclic Chemistry

https://doi.org/10.1002/jhet.2509

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