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RESEARCH PRODUCT

Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability.

Andrés E. GoetaVirginie NielAna GaletJosé Antonio RealM. Carmen MuñozAmber L. Thompson

subject

Allosteric effectSpin crossoverChemical physicsChemistryNanotechnologyGeneral ChemistryState (functional analysis)sense organsGeneral MedicineCatalysisOptical bistability

description

A net change: A fully reversible ligand substitution involving coordination/ uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three-dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin-crossover transition; the compound shows magnetic and chromatic bistability (see picture).

yearjournalcountryeditionlanguage
2003-08-18Angewandte Chemie (International ed. in English)
10.1002/anie.200351853https://pubmed.ncbi.nlm.nih.gov/12923837