From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic-organic 1D helical polymeric anion receptors

6533b85bfe1ef96bd12bac81

RESEARCH PRODUCT

From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic-organic 1D helical polymeric anion receptors

José M. Llinares Laura García-españa Kari Rissanen Pilar Navarro Fangfang Pan Javier Pitarch-jarque Raquel Belda Enrique García-españa

subject

kemia Chemistry Stereochemistry Coordination polymer Metal ions in aqueous solution Cryptand receptors Protonation Pyrazole chemistry Inorganic Chemistry chemistry.chemical_compound Monomer Polymer chemistry Polyamine Receptor ta116

description

We report a novel 1-D helical coordination polymer formed by protonated polyamine 1H-pyrazole cryptands interconnected by Cu2+ metal ions that are able to encapsulate anionic species behaving as a multianion receptor. Switching from a monomeric receptor to a polymeric receptor is activated by metal ions and pH.

year	journal	country	edition	language
2015-04-08	Dalton Transactions 44: 7761-7764 (2015)

10.1039/c5dt00763a http://hdl.handle.net/10261/115128

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