6533b85bfe1ef96bd12bb49d

RESEARCH PRODUCT

Synthesis of brominated tetrathiafulvalenes via phosphite-mediated cross-coupling

Pablo GaviñaConcha Bosch-navarroSergio TatayAntonio Alberola

subject

chemistry.chemical_classificationKetoneBromineHalogenationLithiationChemistryMechanical EngineeringMetals and AlloysCross reactionschemistry.chemical_elementHalogenationCondensed Matter PhysicsChemical synthesisElectronic Optical and Magnetic MaterialsCoupling (electronics)Brominated tetrathiafulvalenesPhosphite cross-couplingMechanics of MaterialsPolymer chemistryMaterials ChemistryOrganic chemistry

description

The synthesis of polybrominated tetrathiafulvalenes (TTF-Brn, 2-4) containing 2-4 bromine atoms via phosphite-mediated cross-coupling of bromo-substituted 1,3-dithiole-2-thiones and 1,3-dithiole-2-ones is reported. © 2010 Elsevier B.V.

https://doi.org/10.1016/j.synthmet.2010.06.001