6533b85bfe1ef96bd12bb691
RESEARCH PRODUCT
A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles
Xiao-yu CaoJean-marie LehnKari RissanenLydia BrelotJack HarrowfieldLuca Russosubject
010405 organic chemistryChemistryHydrogen bondStereochemistryHydrazineAcylhydrazineSolid-stateGeneral ChemistrySelf recognitionCrystal structure010402 general chemistryCondensed Matter Physics01 natural sciences3. Good health0104 chemical scienceschemistry.chemical_compoundOxygen atomPolymer chemistryMoiety[CHIM]Chemical SciencesGeneral Materials Scienceta116ComputingMilieux_MISCELLANEOUSdescription
Self-recognition within the crystal lattices of three functionalised macrocycles results in the formation of arrays of remarkably similar hermaphroditic pairs of macrocycles. In the case of two of the macrocycles containing acylhydrazine substituents, a hitherto unknown recognition pattern is found in the interaction of the hydrazine moiety with crown-ether oxygen atoms.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-01-01 |