(Dimethylformamide)dioxobis(pentane-2,4-dionato)uranium(VI)

6533b85cfe1ef96bd12bc7f7

RESEARCH PRODUCT

(Dimethylformamide)dioxobis(pentane-2,4-dionato)uranium(VI)

Juhani Huuskonen Kari Raatikainen Kari Rissanen

subject

Pentane chemistry.chemical_compound chemistry Atom chemistry.chemical_element Dimethylformamide General Materials Science General Chemistry Uranium Condensed Matter Physics Medicinal chemistry

description

The title complex, [UO2(C5H7O2)2(C3H7NO)], was obtained as an unexpected product from our attempts to prepare UIV complexes with imine-type ligands. The title complex was also prepared directly from [UO2(OAc)2]·2H2O, pentane-2,4-dione and DMF. The UVI atom has a pentagonal-bipyramidal geometry and is surrounded by seven O atoms. The bond distances and angles are similar to those found previously in similar structures.

year	journal	country	edition	language
2007-01-10	Acta Crystallographica Section E Structure Reports Online

https://doi.org/10.1107/s1600536807000141

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