6533b85cfe1ef96bd12bd59a

RESEARCH PRODUCT

Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of nanogel vectors

Maria Antonietta SabatinoSonia LanzalacoIgnasi SirésAlessandro GaliaClelia DispenzaOnofrio Scialdone

subject

Radicals (Chemistry)PolymersRadical02 engineering and technologyengineering.material010402 general chemistryElectrosynthesisDSA01 natural scienceslcsh:ChemistryNanogelPolymer chemistryElectrochemistrychemistry.chemical_classificationDiamondOxidació electroquímicaRadicals (Química)Electrogenerated hydroxyl radicalPolymer021001 nanoscience & nanotechnology0104 chemical sciencesAnodePolímersPolymer modificationElectrolytic oxidationlcsh:Industrial electrochemistrylcsh:QD1-999chemistryElectro-Fentonengineering0210 nano-technologyBDDlcsh:TP250-261Nanogel

description

A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2+ regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone). Keywords: Electrogenerated hydroxyl radicals, BDD, DSA, Electro-Fenton, Polymer modification, Nanogel

yearjournalcountryeditionlanguage
2016-12-10
10.1016/j.elecom.2015.12.005http://hdl.handle.net/2445/164861