Baeyer−Villiger Oxidation with Potassium Peroxomonosulfate Supported on Acidic Silica Gel

6533b85dfe1ef96bd12bdf40

RESEARCH PRODUCT

Baeyer−Villiger Oxidation with Potassium Peroxomonosulfate Supported on Acidic Silica Gel

María Elena González-núñez Rossella Mello Andrea Olmos Gregorio Asensio

subject

Chemistry Silica gel Potassium Organic Chemistry chemistry.chemical_element General Medicine Potassium peroxymonosulfate Catalysis Baeyer–Villiger oxidation chemistry.chemical_compound Hydrolysis Reagent Organic chemistry Dichloromethane

description

[reaction: see text] Potassium peroxomonosulfate deposited onto silica SiO2 x KHSO5 efficiently reacts with ketones in dichloromethane at room temperature to give the corresponding esters or lactones in quantitative yields. This method avoids hydrolysis of the reaction products. The Baeyer-Villiger reaction is catalyzed by potassium hydrogensulfate present in the supported reagent.

year	journal	country	edition	language
2005-11-23	The Journal of Organic Chemistry

https://doi.org/10.1021/jo051614v

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