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RESEARCH PRODUCT
Magnetic Core–Shell Nanoparticles as Carriers for Olefin Dimerization Catalysts
Axel H. E. MüllerAxel H. E. MüllerThomas M. RuhlandHelmut G. AltJulian R. V. Langsubject
inorganic chemicalschemistry.chemical_classificationHydrosilylationNanoparticleAlkynechemistry.chemical_elementPhotochemistryCycloadditionCatalysisInorganic Chemistrychemistry.chemical_compoundNickelchemistryotorhinolaryngologic diseasesClick chemistryMoietydescription
We report the covalent support of functionalized nickel complexes on magnetic core–shell hybrid particles γ-Fe2O3/SiO2. Two completely different ways of connecting the particle with these nickel complexes were carried out. The first approach used the hydrosilylation method between the alkene-substituted nickel complex and a silane. In a second approach, the particles were connected with the complexes by means of click chemistry (copper-catalyzed Huisgen 1,3-dipolar cycloaddition). For this purpose, the nickel complexes were substituted with an alkyne moiety. Transmission and scanning electron microscopies, energy-dispersive X-ray diffraction, and FTIR spectroscopy were the methods employed to characterize the successful heterogenization of the nickel complexes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-02-18 | European Journal of Inorganic Chemistry |