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RESEARCH PRODUCT
[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors
José Antonio RealChristophe FaulmannStéphane DorbesLydie Valadesubject
UNESCO::QUÍMICASpin transitionSalt (chemistry)Mineralogy:QUÍMICA [UNESCO]Fe(sal2-trien)][Ni(dmit)2CatalysisIonSpin crossoverMaterials ChemistryRedox activeElectrical conductorchemistry.chemical_classificationMolecular conductorsUNESCO::QUÍMICA::Química inorgánicaMolecular conductors ; Spin transition ; Salt based ; Fe(sal2-trien)][Ni(dmit)2Metals and AlloysSpin transitionSalt basedGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryCeramics and Compositesdescription
A cooperative spin transition behaviour with a wide hysteresis loop (30 K) around 240 K has been observed, for the first time, in a salt based on the redox active [Ni(dmit)2]¯, anion and the [Fe(sal2-trien)]+ spin crossover cation. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-12-23 | Chemical Communications |